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PAE Polymers

Xerox Poly(Arylene Ether) and Poly (Arylene Ether Ketone) polymers are new advanced materials invented by Xerox researchers and developed and scaled-up at Xerox Research Centre of Canada. This exciting new technology, which has many potential applications, is now available for licensing by chemical and polymer manufacturers.

Technology Description

Poly(arylene ether)s (PAE) photoresist materials are based upon high performance polymers with photo- and thermo-sensitive groups that enable them to be patterned into highly defined three-dimensional surface structures. These photoresists are resistant to harsh chemical and thermal environments. They have unique mechanical and physical properties relative to other currently available photoresist materials.

PAE Polymer Structure



Xerox has developed not only the synthetic chemical processes to make PAE photoresist but also the necessary methods to formulate and form Micro Electro Mechanical System (MEMS) devices with it. While this material was developed for use in proprietary inkjet print heads its potential applications are much broader. In fact Xerox can customize PAE polymers for mechanical properties, solvent resistance or surface properties relative to specific application contexts.

Comparision of Polymer Profiles

The photos below show ink jet nozzles structures made with competing polymers. Polyimide is on the left vs. PAE on the right. Maximum aspect ratio for the polyimide is 2:1 and the maximum aspect ratio for the PAE is 3:1. Z direction shrinkage for the polyimide is 55% and z direction shrinkage for the PAE is 12%. Note that PAE is able to produce finer (smaller diameter) nozzles with significantly less shrinkage.





Xerox High Performance PAE Polymers provide:

Thermal stability
Hydrolytic stability
Solvent resistance
Low shrinkage during curing
Adhesion
Chemical stability/resistance

Intellectual Property Summary

For your convenience and review, we have provided a sample of selected patents from our portfolio.

U.S. 6,187,512
Process for halomethylation of high performance polymers
U.S. 6,184,263
Blends containing photosensitive high performance aromatic ether curable polymers
U.S. 6,174,636
Imaging members containing arylene ether alcohol polymers
U.S. 6,139,920
Photoresist compositions
U.S. 6,124,372
High performance polymer compositions having photosensitivity-imparting substituents and thermal sensitivity-imparting substituents
U.S. 6,117,967
Arylene ether alcohol polymers
U.S. 6,090,453
Halomethylated high performance curable polymers
U.S. 6,087,414
Process for direct substitution of high performance polymers with unsaturated ester groups
U.S. 6,020,119
Process for halomethylation of high performance polymers
U.S. 6,007,877
Aqueous developable high performance photosensitive curable aromatic ether polymers
U.S. 5,994,425
Curable compositions containing photosensitive high performance aromatic ether polymers
U.S. 5,958,995
Blends containing photosensitive high performance aromatic ether curable polymers
U.S. 5,945,253
High performance curable polymers and processes for the preparation thereof
U.S. 5,907,001
Process for the preparation of photopatternable polymers
U.S. 5,889,077
Process for direct substitution of high performance polymers with unsaturated ester groups
U.S. 5,882,814
Imaging members containing high performance charge transporting polymers
U.S. 5,874,192
Imaging members with charge transport layers containing high performance polymer blends
U.S. 5,863,963
Halomethylated high performance curable polymers
U.S. 5,849,809
Hydroxyalkylated high performance curable polymers
U.S. 5,814,426
Imaging members containing high performance polymers
U.S. 5,761,809
Process for substituting haloalkylated polymers with unsaturated ester, ether, and alkylcarboxymethylene groups
U.S. 5,753,783
Process for haloalkylation of high performance polymers
U.S. 5,739,254
Process for haloalkylation of high performance polymers
U.S. 5,731,078
Developing apparatus and coated developer roller

For Licensing Information

To learn more about licensing the PAE Polymers technology, contact Xerox.

Read more about the PAE Polymers technology in this manuscript (115Kb).


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